Numerical simulations have been done to delineate transport effects on the electrodeposition of heavy ions in the deep cavities typically fabricated by the LIGA process. Both forced convection and buoyancy-driven natural convection have been considered. Flow patterns and deposition rates have been calculated for a range of electrode reaction rates, forced flow Reynolds numbers, Rayleigh numbers and cavity aspect ratios. The results show that free convection is a significant player in the transport-limited regime, and substantially increases deposition rates, even for modest Rayleigh numbers. For high Rayleigh numbers, the flows are found to be unsteady, and may further increase deposition rates.
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