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We demonstrate ultralong room temperature phosphorescence from aggregates of an organic semiconductor by managing competing effects of aggregate-induced enhancement and quenching with a simple and scalable processing technique. These results are in contrast to conventional ultralong room temperature phosphors which employ single crystals or isolated molecules in a rigid host, thus imposing deleteriously strict molecular design and processing constraints. The photophysical mechanisms for aggregate-enhanced emission and quenching are discussed.
Jesse A. Wisch,Marko R. Ivancevic,Quinn C. Burlingame,Yueh-Lin Loo, andBarry P. Rand
"Balancing aggregate-induced quenching and emission to achieve ultralong room temperature phosphorescence in an organic semiconductor", Proc. SPIE PC12659, Organic and Hybrid Light Emitting Materials and Devices XXVII, PC126590X (1 October 2023); https://doi.org/10.1117/12.2676829
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Jesse A. Wisch, Marko R. Ivancevic, Quinn C. Burlingame, Yueh-Lin Loo, Barry P. Rand, "Balancing aggregate-induced quenching and emission to achieve ultralong room temperature phosphorescence in an organic semiconductor," Proc. SPIE PC12659, Organic and Hybrid Light Emitting Materials and Devices XXVII, PC126590X (1 October 2023); https://doi.org/10.1117/12.2676829