The ability to identify explosives by ultrasonic spectra up to 45 kHz has been investigated for forensic and anti-terror applications. To lower the threshold for laser initiation, nontrivial and well-known azides, CTAP, HMDT, ETN, HMX and other energetic materials have been synthesized. Upon initiation of copper azide by Nd:YAG laser with 11 ns pulsewidth, a threshold of only ~80 μJ was reached, and for 50 μs pulses of laser diode it was ~300 μJ, which is consistent with the thermal initiation nature. Significant differences were found in the spectrum of high-frequency acoustic and ultrasonic vibrations for various energetic materials and bilayer structures. The effective frequency range for the dissociation of copper azide, silver azide and HMTD is limited by ~27 kHz. The spectra of bilayer structures demonstrate suppression of the characteristic lines of copper azide and enrich the spectrum in the ~27 – 45 kHz range: ETN appears in relatively wide bands, while HMX modulates the spectrum with periodic ~3 kHz bands. If successful, the discovered patterns can be used in disaster forensics.
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