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We report photoreflectance studies ofMOCVD grown doped GaAs at the higher energy
transition E1( 2.9 eV). We are especially interested in the variation ofboth the energy position
and the broadening parameter F of the E1 transition with doping concentration. Above 1 x
10'8cin3 for Si:GaAs and ' 7 X 1018 for Zn:GaAs, we observe an increasing overlap of B1 and
E1 + Li structures. Evaluation of r based on curve fitting of the KramersKronig analysed
data shows a nearly linear relation between F and the logarithm of carrier concentration. This
observation has potential application in the determination of carrier concentration for heavily
doped films.
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Alireza Badakhshan, Robert Glosser, Steve Lambert, "Photoreflectance of doped GaAs beyond the band gap," Proc. SPIE 1286, Modulation Spectroscopy, (1 August 1990); https://doi.org/10.1117/12.20867