Orientational relaxation of spherical top molecules in gases and liquids: effect of collision intensity

A. P. Blokhin; M. F. Gelin

doi:10.1117/12.267784

3 March 1997 Orientational relaxation of spherical top molecules in gases and liquids: effect of collision intensity

A. P. Blokhin, M. F. Gelin

Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267784
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation

Abstract

In order to study the influence of correlation of the angular momenta before and after collision on the course of orientational relaxation of spherical top molecules, a Markovian master equation with the collision kernel by Keilson and Storer is considered. The equation is solved analytically in the case of the complete angular momentum reorientation due to a collision. The results obtained allow one to establish the upper and the lower limit of the time development of the orientational correlation functions.

Citation Download Citation

A. P. Blokhin and M. F. Gelin "Orientational relaxation of spherical top molecules in gases and liquids: effect of collision intensity", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); https://doi.org/10.1117/12.267784

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available