Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)[sub]x[/sub] (X = 2,3,4)

A J Ouderkirk; T A Seder; Eric Weitz

doi:10.1117/12.939425

31 May 1984 Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)_x (X = 2,3,4)

A J Ouderkirk, T A Seder, Eric Weitz

Proceedings Volume 0458, Applications of Lasers to Industrial Chemistry; (1984) https://doi.org/10.1117/12.939425
Event: 1984 Los Angeles Technical Symposium, 1984, Los Angeles, United States

Abstract

An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(C0)₃ and Fe(C0)₄ with CO are also reported. The photophysics of Fe(C0)_x formation is discussed.

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A J Ouderkirk, T A Seder, and Eric Weitz "Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)_x (X = 2,3,4)", Proc. SPIE 0458, Applications of Lasers to Industrial Chemistry, (31 May 1984); https://doi.org/10.1117/12.939425

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