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The single-crystalline GaN nanowires play crucial roles in the pursuit of modern nanophotonic and nanoelectronic devices. Here, a photoelectrochemical-type ultraviolet photodetector consisting of GaN p-n junction nanowires as photoelectrodes is constructed. It is found that two competing charge transport processes co-determine the photoresponsive behavior of the device. Furthermore, the surface platinum (Pt) decoration has successfully tuned the charge transfer dynamics by enhancing the charge transport efficiency of the one process at the surface, resulting in a twenty-fold increase of the photocurrent. Theoretical calculations reveal that the high photoresponse benefits from the newly formed electronic states at the Pt/GaN interface and the optimized hydrogen adsorption energy.
Shi Fang,Danhao Wang, andHaiding Sun
"High quality MBE-grown GaN p-n nanowires and their carrier transport control for photoelectrochemical ultraviolet photodetection", Proc. SPIE PC12001, Gallium Nitride Materials and Devices XVII, PC1200117 (5 March 2022); https://doi.org/10.1117/12.2605967
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Shi Fang, Danhao Wang, Haiding Sun, "High quality MBE-grown GaN p-n nanowires and their carrier transport control for photoelectrochemical ultraviolet photodetection," Proc. SPIE PC12001, Gallium Nitride Materials and Devices XVII, PC1200117 (5 March 2022); https://doi.org/10.1117/12.2605967