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Luminescence of Bi3TeBO9 micro-crystals doped with Nd3+ ions
D. Kasprowicz,1 T. Zhezhera,1 P. Głuchowski,2 M. Chrunik,3 A. Majchrowski,3
1Faculty of Materials Engineering and Technical Physics, Poznan University of Technology, Piotrowo 3, 60-965 Poznań, Poland,
2Institute of Low Temperature and Structure Research of Polish Academy of Sciences, Okólna 2, 50-422 Wrocław, Poland
3Institute of Applied Physics, Military University of Technology, Kaliskiego 2, 00-908 Warsaw, Poland,
е-mail: dobroslawa.kasprowicz@put.poznan.pl
Bi3TeBO9 crystal is an excellent nonlinear optical material as well as an efficient host matrix for luminescent rare earth ions.1,2 Investigated Bi3TeBO9 crystalline powders were synthesized by means of the modified Pechini method. The vibrational properties of Bi3TeBO9 were studied using µ-Raman spectroscopy.3 Moreover, Bi3TeBO9 powders doped with Nd3+ ions show the efficient near-infrared quantum cutting process by cooperative down-conversion of active Bi3+ and Nd3+ ions. As a result, the investigated systems efficiently concentrate the ultraviolet/visible radiation in the near-infrared spectral range and can be potentially used as effective spectral converters in new multi-functional miniaturized optical devices.
Acknowledgement
This work was supported by the Research Project of the Polish Ministry of Sciences and Higher Education 0511/SBAD/2151.
References
[1] M. Xia, X. Jiang, Z. Lin, R. Li, J. Am. Chem. Soc. Journal, 2016, 138, 14190–14193.
[2] M. Daub, M. Krummer, A. Hoffmann, L. Bayarjargal, H. Hillebrecht, Journal, Chem Eur J, 2016, 22, 1–8.
[3] D. Kasprowicza, T. Zhezhera, A. Lapinski, M. Chrunik, A. Majchrowski, A.V. Kityk, Ya. Shchur,
J. Alloys Comp., 2018, 782, 488–495.
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