Presentation
18 June 2024 Strongly thermochromic behavior of doped VO2 switching at low temperature for spacecraft thermal control
William Ravisy, Thomas Pouit, Bruno Bras, Szilvia Szmolka, Philipp Hager, Laurent Dubost
Author Affiliations +
Abstract
Thermochromic materials are of high interest for their potential applications in spacecraft thermal control, with systems exhibiting variable emissivity able to manage the heat rejection and absorption. VO2 presents one of the most prominent technological options for thermochromic behaviors, with a transition temperature around 68°C limiting its practical utility for spacecraft thermal control notably. Here, we report the synthesis of strongly thermochromic tungsten doped vanadium dioxide coatings on silicon wafers obtained in an industrial-size vacuum deposition chamber. Samples with various W doping rates were deposited by magnetron sputtering, exhibiting thermochromic transition temperatures from 38°C to as low as 5°C, with optical transmission contrasts at a wavelength of 12 µm maintained between 40% and 58%, enabling enhanced control of heat exchange at low temperature and broader usability. The variable emissivity radiators were measured to have emissivity contrasts up to 40%, with transition temperatures as low as 10°C, demonstrating the potential use of the VO2-based thermochromic coating.
Conference Presentation
© (2024) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
William Ravisy, Thomas Pouit, Bruno Bras, Szilvia Szmolka, Philipp Hager, and Laurent Dubost "Strongly thermochromic behavior of doped VO2 switching at low temperature for spacecraft thermal control", Proc. SPIE PC13020, Advances in Optical Thin Films VIII, PC130200P (18 June 2024); https://doi.org/10.1117/12.3023007
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KEYWORDS
Emissivity

Space operations

Switching

Control systems

Optical coatings

Vanadium

Doping

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