Detection of volatile organic compounds (VOCs) with particular attention to the BTEX group consisting of benzene, toluene, ethylbenzene, and xylene has risen as an important task in fields as environmental monitoring and breath analysis. Sensors based on optical detection techniques may represent an alternative to traditional approaches. However, optical sensing has been limited in terms of measurements selectivity as BTEX point out absorption features around 3.3 μm, where strong interferences from hydrocarbons occur. This issue can be eliminated operating at longer wavelength in the region from 13 to 15 μm, where BTEX show distinct and isolated absorption features. However, the investigations in this region have been limited by the lack of suitable laser sources as well as by the low performances of commercial detectors. In this work, a new approach to benzene detection is proposed, employing a long wavelength InAs-based QCL as light source and a quartz tuning fork as detector for TDLAS measurements, in light-induced thermoelastic spectroscopy (LITES) detection scheme. Analyte detection in the range of hundreds of part-per-billion with a shoe-box size design is demonstrated.
We report on the development of Quartz-Enhanced Photoacoustic Spectroscopy (QEPAS) technology to detect 8 different air pollutants, namely CH4, NO2, CO2, N2O, CO, NO, SO2 and NH3, with the same acoustic detection module and interchangeable laser sources, to prove the modularity of the technique as well as the adaptability to different lasers. For each gas species, the fine structure of the infrared absorption bands has been simulated by using HITRAN database. Each gas species was detected with an ultimate detection limit well below their typical natural abundance in air even with signal integration time as low as 0.1 s.
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