KEYWORDS: Near field scanning optical microscopy, Near field optics, Solar cells, Thin film solar cells, Optical microscopy, Near field scanning optical microscopy, Optical microscopy, Crystals, Light wave propagation, Silicon, Near field, Absorption
The efficiency of thin-film solar cells strongly depends on the plasmonic structures, cloaking, and especially the microscopic and nanoscopic material inhomogeneity and surface topography of the absorber. However, the understanding of the latter requires optoelectronic characterization on a nanoscale. In this study, by applying an aperture-type scanning near-field optical microscope (SNOM) in illumination mode, direct photocurrent measurements with sub-100 nm resolution were performed on randomly textured hydrogenated microcrystalline silicon (μc-Si:H) thin-film solar cell, flat μc-Si:H thin-film solar cell and flat hydrogenated amorphous silicon (a-Si:H) thin-film solar cell in order to investigate the influence of material inhomogeneity and surface topography on the local photocurrent generation. While in case of the randomly textured μc-Si:H solar cell, contrary behaviors of the photocurrent response between short and long wavelengths were identified, the same correlation between the photocurrent signal and the surface topography was observed for the two flat solar cells at all wavelengths. The measurement results can be explained by a combination of two dominant effects, (i) local light coupling into the sample and (ii) light propagation inside the sample. By this study, on the one hand the importance of surface texturing as a concept to increase the efficiency is demonstrated. On the other hand, the influence of the interaction between the SNOM probe and the surface on the photocurrent measurements has been investigated.
In thin optoelectronic devices, like organic light emitting diodes (OLED) or thin-film solar cells (TFSC), light propagation, which is initiated by a local point source, is of particular importance. In OLEDs, light is generated in the layer by the luminescence of single molecules, whereas in TFSCs, light is coupled into the devices by scattering at small surface features. In both applications, light propagation within the active layers has a significant impact on the optical device performance. Scanning near-field optical microscopy (SNOM) using aperture probes is a powerful tool to investigate this propagation with a high spatial resolution. Dual-probe SNOM allows simulating the local light generation by an illumination probe as well as the detection of the light propagated through the layer. In our work, we focus on the light propagation in thin silicon films as used in thin-film silicon solar cells. We investigate the light-in-coupling from an illuminating probe via rigorous solution of Maxwell's equations using a Finite-Difference Time-Domain approach, especially to gain insight into the light distribution inside a thin layer, which is not accessible in the experiment. The structures investigated include at and structured surfaces with varying illumination positions and wavelengths. From the performed simulations, we define a "spatial sensitivity" which is characteristic for the local structure and illumination position. This quantity can help to identify structures which are beneficial as well as detrimental to absorption inside the investigated layer. We find a strong dependence of the spatial sensitivity on the surface structure as well as both the absorption coefficient and the probe position. Furthermore, we investigate inhomogeneity in local light propagation resulting from different surface structures and illumination positions.
KEYWORDS: Solar cells, Thin film solar cells, Nanostructures, Silver, Prototyping, External quantum efficiency, Plasmonics, Amorphous silicon, Diffraction, Atomic force microscopy
We experimentally investigate the light-trapping effect of plasmonic reflection grating back contacts in prototype hydrogenated amorphous silicon thin-film solar cells in substrate configuration. These back contacts consist of periodically arranged Ag nanostructures on flat Ag reflectors. We vary the period, unit cell, and width of the nanostructures to identify design strategies for optimized light trapping. First, a general correlation between the reduction of the period of the nanostructures down to 550 nm and an increase of the absorptance, as well as external quantum efficiency is found for various unit cells formed by nanostructures. Second, increasing the width of the nanostructures from 200 to 350 nm, an enhanced light-trapping effect of the thin-film solar cells is found independent of the period. As a result, we identify a design for improved light trapping for the given solar cell parameters within the considered variations. It consists of thin-film solar cells applying a combination of a period of 600 nm and a structure width of 350 nm. The implementation of back contacts with this configuration yields enhanced power conversion efficiency as compared to reference solar cells processed on conventionally used randomly textured substrates. In detail, the enhancement of the short-circuit current density from initially 14.7 to initially 15.6 mA/cm2 improves the power conversion efficiency from 9.1 to 9.3%.
KEYWORDS: Thin film solar cells, Solar cells, Nanostructures, Plasmonics, Silver, Prototyping, External quantum efficiency, Amorphous silicon, Atomic force microscopy, Diffraction
In this study, we experimentally investigate the light-trapping effect of plasmonic reflection grating back contacts in prototype hydrogenated amorphous silicon thin-film solar cells in substrate configuration. The plasmonic reflection grating back contacts consist of periodically arranged Ag nanostructures on flat Ag reflectors. By varying the geometrical parameters of these back contacts, design strategies for optimized light trapping are identified. First, a general correlation between a reduction of the period of the plasmonic reflection grating back contact and an increase of the absorptance as well as external quantum efficiency is found for various unit cells of the nanostructures i.e. square unit cell, hexagonal unit cell and face-centered unit cell. Second, the width of the nanostructures is varied. With increasing width, an enhanced light-trapping effect of the thin-film solar cells is found independent of the period. As a result, an optimized design for improved light trapping in the studied thin-film solar cells is a combination of a period of 600 nm and a structure width of 350 nm. Solar cells fabricated on plasmonic reflection grating back contacts with this optimized configuration yield enhanced power conversion efficiencies as compared to reference solar cells processed on state-ofthe- art randomly textured substrates. In detail, the power conversion efficiency is enhanced by around 0.2 % from 9.1 % to 9.3 %. This increase is largely due to the enhancement of the short-circuit current density of around 7 % from 14.7 mA/cm2 to 15.6 mA/cm2.
To investigate light propagation and near-field effects above structured surfaces, scanning near-field optical microscopy is a powerful tool providing access to the near-field intensity. These measurements can be combined with rigorous solving of Maxwell's equations to gain insight into light propagation inside the sample, which is not accessible via experiment. However, we find differences between the intensity distribution obtained via experiment and that observed in the simulation at a constant distance of 20 nm above the surface, which corresponds to the typical surface-to-probe distance in the experiment. A first explanation was given by topographic artefacts [Proc. SPIE 8789, 87890I (2013)]. To better understand the interaction between sample and probe in regard to light propagation, we include the probe in high-resolution simulations of different structures, with the position of the (finite-sized) probe resulting from its placement above each structure. While there is a visible difference in the overall light distribution of the system, caused by the probe, the relative intensity at the position of the probe is shown to be in very good agreement to the intensity in a system without the probe. This has been found for many probe positions along the surface of the structure. This result is applicable to many systems in different fields of research which use such measurements for obtaining information about near-field effects of samples. We show an application for thin-film photovoltaics, where light scattering textured surfaces are used to increase the path length of photons in the absorber layer to increase device performance.
KEYWORDS: Near field scanning optical microscopy, Computer simulations, Finite-difference time-domain method, Zinc oxide, Near field, Atomic force microscopy, Thin film solar cells, Thin film devices, Coating, Light scattering
Scanning near-field optical microscopy (SNOM) is a powerful tool providing measurement of the near-field intensity of nano-structured surface layers. These measurements can be combined with rigorous solving of Maxwell's equations to gain insight into light propagation inside the layer. However, there are often major differences between the simulated near-field intensity directly above the surface and SNOM measurements. The SNOM measurements are being performed in a way that sample and probe have a distance of about 20 nm at their closest point, therefore the finite size of the probe has a severe impact on the measurement, e.g. for textured surfaces. Any steep flank present in the topography leads to an increased distance between the aperture of the probe and the sample surface, since the shortest distance between sample and probe occurs at the side of the tip. This behavior modifies the measurement at all points where the geometry does not allow for the aperture to be placed 20 nm over the topography, since another part of the probe would get in contact with the surface. To account for these topography artifacts in our simulations, we developed an algorithm to calculate the height of the probe above each point of the surface. Taking this position into account for each point of the topography measurement, we are able to obtain an intensity distribution at the same positions as the SNOM measurement. This intensity distribution shows a much better agreement to experiment than assuming a constant distance of 20 nm from the surface. We illustrate this algorithm and its consequences for comparisons between SNOM measurements and simulation using the textured transparent front contact of a silicon-based thin-film solar cell as an example. In such devices, the absorber layer of the cell is typically thinner than the absorption length of the incident light, especially in the long wavelength region. Due to the texture, the effective light path can be prolonged, and near-field measurements allow for an insight into light intensity close to the interface as well as guided modes.
Light trapping is a key issue for high efficiency thin-film silicon solar cells. The authors present three-dimensional electromagnetic simulations of an n-i-p substrate-type microcrystalline silicon solar cell applying a plasmonic reflection grating back contact as a novel light-trapping structure. The plasmonic reflection grating back contact consists of half-ellipsoidal silver nanostructures arranged in square lattice at the back contact of thin-film silicon solar cells. Experimental results of prototypes of microcrystalline silicon thin-film solar cells showed significantly enhanced short-circuit current densities in comparison to flat solar cells and, for an optimized period of the plasmonic reflection grating back contact, even a small enhancement of the short-circuit current density in comparison to the reference cells applying the conventional random texture light-trapping structure. The authors demonstrate a very good agreement between the simulated and experimental spectral response data when taking experimental variations into account. This agreement forms an excellent basis for future simulation based optimizations of the light-trapping by plasmonic reflection grating back contacts. Furthermore, from the simulated three-dimensional electromagnetic field distributions detailed absorption profiles were calculated allowing a spatially resolved evaluation of parasitic losses inside the solar cell.
The influence of the front texture of an etched transparent conductive oxide with crater-like structures of various
sizes on the absorption of a thin amorphous silicon (a-Si:H) layer is investigated by rigorous optical simulations
as part of two simplified systems: A simplified single junction device, using a perfect metal as back contact
and a top cell of an amorphous/microcrystalline silicon tandem device, using a microcrystalline silicon halfspace
adjacent to the amorphous layer. The texture is modified by stretching either in height or laterally and the
average absorption in the a-Si:H layer is investigated relative to the original structure. We investigate the average
absorption for each wavelength as well as the total absorption, weighted with an AM1.5g spectrum. Furthermore,
the local absorption distribution inside the a-Si:H layer is examined to improve the understanding of local texture
features and their influence on absorption and cell performance. For both modifications, an optimal point can be
found to improve the absorption in the amorphous layer by up to 15% and 6% for a simplified single junction and
tandem top cell, respectively. In case of the top cell of the simplified tandem device, it is found that additionally,
the transmission into the microcrystalline silicon can be improved. Also, the local absorption distribution shows
that there is an optimal size of the surface craters for all modifications, while steeper crater rims in general lead
to higher absorption.
KEYWORDS: Scattering, Light scattering, Silicon, Air contamination, Solar cells, Thin film solar cells, Interfaces, Thin films, Silicon solar cells, Transparent conductors
The scattering of light by the textured transparent conductive oxide (TCO) in thin-film silicon solar cells is
frequently described by transmission haze and angular intensity distribution (AID) at the interface between the TCO
and air. The scattering is expected to improve the light trapping and, therefore, the absorption of the solar cell. Using
these scattering properties as input parameters for the electrical modeling of thin-film solar cells leads to significant
deviations from the measurements for short circuit current densities. The major disadvantage of the AID measurement
at the TCO/air interface is that in real thin-film silicon solar cells the TCO/Si interface is relevant. We use a
model that is based on scalar scattering theory to calculate the scattering properties at the transition into air and into
silicon. The model takes into account the measured surface topography and the optical constants of the adjacent
media. For a series of μc-Si:H cells on ZnO:Al with different surface topographies, AID and the transmission haze
into a μc-Si:H half space are calculated. From these results, a quantity is derived that describes the scattering
efficiency. This quantity is compared to the short circuit current densities of μc-Si:H solar cells showing good
agreement. It will be shown that for artificially modified textures an increase in the short-circuit current density and
thus, the efficiency of thin-film silicon solar cells can be achieved.
KEYWORDS: Solar cells, External quantum efficiency, Plasmonics, Silver, Silicon solar cells, Absorption, Nanostructures, Thin film solar cells, Thin films, Prototyping
Light-trapping is a key issue for high efficiency thin-film silicon solar cells. In this work, the interaction of incident light
with microcrystalline silicon solar cells applying a plasmonic reflection grating back contact is studied with threedimensional
electromagnetic simulations and via the measured spectral response of prototypes. The investigated
plasmonic reflection grating back contact consists of half-ellipsoidal silver nanostructures arranged in square lattice at
the back contact of a n-i-p substrate type microcrystalline silicon solar cell. Experimental results of prototypes of these
solar cells show significantly enhanced short circuit current densities in comparison to flat cells and even a small
enhancement of the short circuit current density in comparison to the conventional random texture light-trapping concept
of thin-film silicon solar cell. A very good agreement was found for the simulated and measured spectral response of the
solar cell. From the simulated three-dimensional electromagnetic field distributions detailed absorption profiles were
calculated allowing a spatially resolved evaluation of parasitic losses inside the n-i-p type microcrystalline silicon solar
cell.
Light management in single and tandem solar cells is becoming increasingly important to optimize the optical
and electro-optical properties of solar cells. After a short introduction to state-of-the-art light management
approaches, different applications of photonic crystals for photon management in solar cells are reviewed
and discussed concerning their applicability. Results on direction- and energy-selective filters for ultra-light-trapping,
intermediate reflectors for optimal current matching in tandem cells, and photonic crystal coating
for fluorescence collectors will be presented and discussed.
Investigations of optical losses induced by localized plasmons in protrusions on silver back contacts of thin-film silicon
solar cells are presented. The interaction of electromagnetic waves with nanoprotrusions on flat silver layers is simulated
with a three-dimensional numerical solver of Maxwell's equations. Spatial absorption profiles and spatial electric field
profiles as well as the absorption inside the protrusions are calculated. The results presented here show that the
absorption of irradiated light at nanorough silver layers can be strongly enhanced by localized plasmonic resonances in
Ag nanoprotrusions. Especially, localized plasmons in protrusions with a radius below 60 nm induce strong absorption,
which can be several times the energy irradiated on the protrusion's cross section. The localized plasmonic resonances in
single protrusions on Ag layers are observed to shift to longer wavelengths with increasing refractive index of the
surrounding material. At wavelengths above 500 nm localized plasmonic resonances will increase the absorption of
nanorough μc-Si:H/Ag interfaces. The localized plasmon induced absorption at nanorough ZnO/Ag interfaces lies at
shorter wavelengths due to the lower refractive index of ZnO. For wavelengths above 500 nm, a high reflectivity of the
silver back contacts is essential for the light-trapping of thin-film silicon solar cells. Localized-plasmon induced losses at
silver back contacts can explain the experimentally observed increase of the solar cell performance when applying a
ZnO/Ag back contact in comparison to a μc-Si:H/Ag back contact.
We introduce a model which allows for the description of scattering properties of randomly textured ZnO
films by evaluating a Fourier surface analysis. The interface is developed into a series of periodic gratings
with well defined diffraction angles. The scattering efficiency is assumed to be the Fourier transform of
the surface profile. This model is applied on different kinds of textures and compared with experimentally
obtained angularly resolved scattering. This Fourier model is extended to obtain the scattering properties
with both spatial and angular resolution which allows the study of the light scattering of individual surface
elements. The identification of structures which scatter light into larger angles is possible. The calculated
scattering properties show a good agreement to the experimentally obtained data. The results are essential
for the further improvement of surface texture to optimize light trapping in thin-film solar cells.
A 3D photonic intermediate reflector for textured micromorph silicon tandem solar cells has been investigated.
In thin-film silicon tandem solar cells consisting of amorphous and microcrystalline silicon with two junctions
of a-Si/c-Si, efficiency enhancements can be achieved by increasing the current density in the a-Si top cell
providing an optimized current matching at high current densities. For an ideal photon-management between
top and bottom cell, a spectrally-selective intermediate reflective layer (IRL) is necessary. We present the
first fully-integrated 3D photonic thin-film IRL device incorporated on a planar substrate. Using a ZnO
inverted opal structure the external quantum efficiency of the top cell in the spectral region of interest could
be enhanced. As an outlook we present the design and the preparation of a 3D self organized photonic crystal
structure in a textured micromorph tandem solar cell.
The efficiency of thin film solar cells can be improved with the addition of a photon down-conversion top layer. This
layer converts incident ultraviolet light of the solar spectrum to visible light, which transmits through the glass and is
efficiently absorbed by the active layer of the solar cell. The results of our investigations of thin dielectric films and
fluorozirconate glass, both doped with Tb3+ ions, are presented. Tb3+ has absorption bands between 250 and 380 nm; the
corresponding emission bands are in the spectral range between 400 and 630 nm. Thin SiO2 and Al2O3 films with 0.04 -
10.18 at.% Tb were prepared by co-sputtering. For both as-deposited film systems, the highest fluorescence intensity is
found for a Tb3+ doping level of approximately 1 at.%; the fluorescence intensity of Tb3+ in SiO2 is higher than that in
Al2O3. Thermal treatment leads to an enhancement of the fluorescence intensity by more than one order of magnitude
and the highest fluorescence intensity is found for 2 at.% Tb for annealed thin SiO2 films containing Tb3+. For
comparison, the absorption and emission properties of Tb3+-doped fluorozirconate glass are investigated for a doping
level of 0.3 at.% Tb.
The realm of nanooptics is usually characterized by the interaction of light with structures having relevant feature sizes
much smaller than the wavelength. To model such problems, a large variety of methods exists. However, most of them
either require a periodic arrangement of a unit cell or can handle only single entities. But there exists a great variety of
functional devices which may have either a spatial extent much larger than the wavelength and which comprise structural
details with sizes in the order of a fraction of the wavelength or they may consist of an amorphous arrangement of
strongly scattering entities. Such structures require large scale simulations where the fine details are retained. In this
contribution we outline our latest research on such devices and detail the computational peculiarities we have to
overcome. Presenting several examples, we show how simulations support the physical understanding of these devices.
Examples are randomly textured surfaces used for solar cells, where guided modes excited in the light absorbing layers
strongly affect the solar cell efficiency, amorphous metamaterials and stochastically arranged nanoantennas. The usage
of computational experiments will be motivated by the unprecedented insight into the functionality of such components.
The progress of 3D photonic intermediate reflectors for micromorph silicon tandem cells towards a first prototype
cell is presented. Intermediate reflectors enhance the absorption of spectrally-selected light in the top cell
and decrease the current mismatch between both junctions. A numerical method to predict filter properties for
optimal current matching is presented. Our device is an inverted opal structure made of ZnO and fabricated
using self-organized nanoparticles and atomic layer deposition for conformal coating. In particular, the influence
of ZnO-doping and replicated cracks during drying of the opal is discussed with respect to conductivity
and optical properties. A first prototype is compared to a state-of-the-art reference cell.
The concept of a 3D photonic crystal structure as diffractive and spectrally selective intermediate filter within
'micromorphous' (a-Si/μc-Si) tandem solar cells has been investigated numerically and experimentally. Our device aims
for the enhancement of the optical pathway of incident light within the amorphous silicon top cell in its spectral region of
low absorption. From our previous simulations, we expect a significant improvement of the tandem cell efficiency of
about absolutely 1.3%. This increases the efficiency for a typical a-Si / μc-Si tandem cell from 11.1% to 12.4%, as a
result of the optical current-matching of the two junctions. We suggest as wavelength-selective optical element a 3D-structured
optical thin-film, prepared by self-organized artificial opal templates and replicated with atomic layer
deposition. The resulting samples are highly periodic thin-film inverted opals made of conducting and transparent zinc-oxide.
We describe the fabrication processes and compare experimental data on the optical properties in reflection and
transmission with our simulations and photonic band structure calculations.
KEYWORDS: Zinc oxide, Amorphous silicon, Near field scanning optical microscopy, Near field optics, Thin film solar cells, Near field, Finite-difference time-domain method, Silicon solar cells, Thin films, Absorption
Randomly textured zinc oxide surfaces with and without amorphous silicon deposited on top are studied by near-field
scanning optical microscopy. By virtue of a three dimensions it allows to access the local light intensity in the entire
spatial domain above the structures. Measurements are compared with large scale finite-difference time-domain
simulations. This study provides new insight into light trapping in thin-film silicon solar cells on a nanoscopic scale.
Light localization on the surface of the textured interface and a focusing of light by the structure further away are
observed as the key features characteristic for such surfaces.
KEYWORDS: Silicon, Photonic crystals, Diffraction, Thin films, Photons, Absorption, Crystals, Thin film solar cells, Optical spheres, Tandem solar cells
We suggest an energy selective and diffractive optical element as intermediate layer in thin-film tandem solar cells. By
adjusting the lattice constant of this photonic crystal, we fitted the optical properties to match a silicon tandem pair. Our
device enhances the pathway of incident light within an amorphous silicon top cell in its spectral region of low
absorption. In this spectral overlap region of the tandem-junction's quantum efficiencies, photons are being transferred
towards the amorphous cell, which leads to an increase in the short-circuit current of the limiting top cell. From our
simulations we expect a current increase of 1.44mA/cm2 for an - amorphous/microcrystalline - silicon tandem cell,
corresponding to improvement of the tandem's absolute efficiency of about 1.3%.
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